HIPS (1)

HIPS Safety Data Sheet

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3. KODAK 3D Printing Filament HIPS 3 Suitable extinguishing media Water, foam, regular dry chemical, carbon dioxide. Unsuitable extinguishing media None known. Specific hazards arising from the chemical Avoid generating dust. Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Hazardous Combustion Products Carbon monoxide, Carbon dioxide, Nitrogen oxides (NOx), S ulphur oxides (SOx) . Levels of fire hazard: Not available Fire fighting procedures and equipments Wear appropriate personal protective equipment (see section 9. EXPOSURE CONTROLS/PERSONAL PROTECTION). Avoid inhalation of smoke or gas when fire fighting. Use self contained breathing apparatus (SCBA) for protection against possible exposure. Isolate hazard area and deny entry. Stay upwind and keep out of low areas. Move con tainer from fire area if it can be done without risk. Cool containers with water until well after fire is out. Special Protective Equipment and Precautions for Firefighters Avoid inhalation of material or combustion by - products. Stay upwind and keep out of low areas. Section 6 . Accidental Release Measures Per sonal Precautions, Protective Equi pment and Emergency procedures Perform in accordance with section 9 . EXPOSURE CONTROLS/PERSONAL PROTECTION . Wear full protective fire fighting gear including self contained breathing apparatus (SCBA) for protection against possible exposure. Methods and Materials for Containment and Cleaning Up Where possible allow leak of molten material to solidify before d isposal in an appropriate container . Dispose in accordance with all applicable regulations. Environmental Precautions Avoid dispersal of spilt material and run off and contact with waterways, drains , sewers and basements or confined areas . If large spills, advise emergency services. Comply with all applicable regulations on spill and release reporting. Section 7 . Handling and Storage H andling Keep away from the molten plastic while printing in case of being burned.

7. KODAK 3D Printing Filament HIPS 7 Proper shipping name: None Hazard class: Not applicable Packing group: None ICAO/IATA: UN - No.: Not regulated for transport of dangerous goods Proper shipping name: None Hazard Class: Not applicable . Packing group: None Section 15 . Regulatory Information U.S. Federal Regulations SARA 313 Not listed OSHA (29CFR 1910.1200) : Not listed EC Classification: Not listed. Issue date : 2017. 10. 28 Disclaimer This SDS, based on current knowledge and experience , contains a general summary of hazards and is consistent with the information provided by the supplier . No liability can be assumed for the accuracy and completeness of this information. The information in this SDS applies for this specific material only. It therefore does not apply for its usage in combination with other materials or ways of processing. It is user’s responsibility to read and understand this information and incorporate it into individual safety programs , according to all legal and regulatory applicable procedures . Smart International gives no warranty whatsoever, including the warrantie s of merchantability or of fitness for a particular purpose. Any product purchased is sold on the assumption the user shall determine the quality and suitability of the product. Smart International expressly disclaims any and all liability for incidental, consequential or any other damages arising out of the use or misuse of this product. No information provided shall be deemed to be a recommendation to use any product in conflict with any existing patent rights.

6. KODAK 3D Printing Filament HIPS 6 respiratory tract. Ingestion : No data available. Not expected to be harmful. Eye/Skin: No data available. Not expected to be harmful. Molten material may cause burns. Genotoxicity : No data available. Not expected to be harmful. Medical Conditions Aggravated by Exposure No data available. Section 12 . Ecological Information Ecotoxicity No data available. Persistence and Degradability No data available. Bioaccumulative Potential No data available. Mobility No data available . Section 13 . Disposal Considerations Disposal methods Dispose of contents/container in accordance with applicable local , regional , national , and / or international laws and regulations. Avoid release to the environment. Incineration should be done in accordance with prevailing municipal, state, and federal laws and standards from local environmental agencies . Section 14 . Transport Information US DOT Information UN/NA numbe r : Not regulated for transport of dangerous goods Proper shipping name : None Hazard class : Not applicable Packing group : None IMDG: UN/Id No.: Not regulated for transport of dangerous goods

1. KODAK 3D Printing Filament HIPS 1 SAFETY DATA SHEET In accordance with paragraph (d) of 29 CFR 1910.1200:2012 Regulation (EU) No. 1907/2006, Section 1. Chemical Product and Company identification Product Name : KODAK 3D Printing Filament HIPS Importer : Smart International Inc. 20 35 Sunset Lake Road Newark, Delaware 19702 USA. Email: support@smart3d.tech USA Emergency Poison Control Hot Line (24/7) : 1 (800) 222 - 1222 o r call your LOCAL POISON CONTROL CENTER . Section 2 . Hazards Identification GHS Classification : Not applicable GHS label elements Hazard symbols : None needed. Signal word : None needed. Hazard statement : None needed. Precautionary statements Prevention: None needed. Response: None needed. Storage: None needed. EU Classification Classification of substance or mixture : REGULATION (EC) No 1272/2008 This product is not classified as dangerous according to EC criteria. Dis posal Dispose of contents/cont ainer in accordance with local/ regional/national/international regulation. OSHA Regulatory Status This product is not considered hazardous by the 2012 OSHA Hazard Communicat ion Standard (29 CFR 1910.1200) Other hazards which do not result in classification : NFPA rating: (0~4 steps) Health=1, Flammability=0, Reactivity=0

4. KODAK 3D Printing Filament HIPS 4 St orage Store at temperatures not e xceeding 50°C/ 122°F. Keep cool . Avoid heat, flames, sparks and other sources of ignition. Keep away from incompatible materials. Incompatible Materials Oxidizing agents. Section 8 . Exposure Controls & Personal Protection Component Exposure limit Exposure limit under ISHL Not applicable ACGIH Not applicable Biological exposure limits Not applicable EU - Occupational Exposure (98/24/EC) - Binding Biological Limit Values and Health Surveillance Measures There are no biological limit values for any of this product's components. Engineering Controls A system of local and/or general exhaust ventilantion system is recommended to keep exposure below the Exposure Limits. Local exhaust ventilation is considered sufficient to effectively remove emissions (dusts and fumes) of the contaminant at its source, preventing dispersion during handling or thermal processing . Personal Protective Equipment Respiratory Protection No respirator is required under normal conditions of use . Under conditions of frequent use or heavy exposure, Respiratory protection may be needed . Eye /face/skin Protection None during normal use. Protect against molten solid by w ear ing protective gloves. Section 9 . Physical & Chemical Properties Appearance: Monofilament, spool Physical State: Solid Odor: Odorless, plastic pH: Not available Freezing point: Not available Melting point: Not available

5. KODAK 3D Printing Filament HIPS 5 Initial Boiling Point/Boiling Ranges : >250 °C Evapourating Rate: Not available Flammability (solid, gas): Not available Upper/Lower Flammability or explosive limits: Not available Vapour pressure: Not available Solubility: Insoluble , soluble in petroleum solvents. Vapour density (Air=1): Not available Relative density: 1.06 Partition coefficient of n - octanol/water: Not available Autoignition Temperature : Not available Decomposition Temperature: Not available Specific Gravity : 0.45 M olecular weight: Not available Section 10 . Stability & Reactivity Reactivity/ Stability This product is chemical stable under recommended storage , handling , use and temperature conditions . Possibility of Hazardous Reaction Will not polymerize . Conditions to Avoid Avoid contact with heat above 20 0°C , sparks, flame or other ignition sources. Materials to Avoid Strong oxidizing agents such as liquid chlorine and concentrated oxygen . Hazardous Decomposition Products G as /steam, oxides of carbon, oxides of nitrogen, HCN, acrylonitrile, styrene monomer . Section 11 . Toxicological Information Information on the likely routes of exposure Inhalation : No data available . Not expected to be harmful. Dust may cause irritation of the upper

2. KODAK 3D Printing Filament HIPS 2 Section 3 . Composition Chemical name: H igh impact polystyrene Chemical Family: Polymer, thermoplastic copolymer. Product Use: Monofilament for FFF 3D Printing * This material satisfies note L of the CLP classification and can be shown to contain less than 3% DMSO extract as measured by IP346. Therefore it is not classified as carcinogenic. Section 4 . First Aid Measures Inhalation : No data available. Not expected to be harmful. Dust may cause irritation of the upper respiratory tract. Ingestion: There were no target organ effects noted following ingestion in animal studies. Eye/Skin: There were no target organ effects noted following dermal exposure in animal studies Did not cause skin allergic reactions in skin sensitization studies using gui nea pigs. Molten material may cause burns. Genotoxicity : Not mutagenic in AMES Test (rat). Notice to Physician It is unlikely that first aid shall be needed if the product is used under ordinary conditions. Treat symptomatically according to victim’s conditions and specifics of incident . Antidote None known. Treat symptomatically and supportively. Section 5 . Fire - fighting Measures Flammability: Autoignition temperature: >200°C Chemical name CAS n./ECL n./EINECS n . Contents (%) Mixture of severely hydrotreated and hydrocracked base oil* 64742 - 54 - 7/ 265 - 157 - 1 65~75 1 - Decene Homopolymer Hydrogenated 68037 - 01 - 4 15~25 Thermoplastic Elastomer 68648 - 89 - 5 5~10 Acrylic copolymer 38747 - 70 - 0 1~5


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